Emerging hybrid technologies have better potential than conventional technology for diversifying the desalination industry, which is presently being dominated by thermal and membrane-based desalination. Notwithstanding the technological maturity of the desalination processes, they remain highly energy-intensive processes and have certain disadvantages. Therefore, the hybridization of thermal and membrane desalination processes holds great attention to mitigate limitations of individual processes in terms of energy consumption, quality and quantity of potable water, overall efficiency and productivity. This paper provides an oversight of conventional and developing desalination technologies, emphasizing their existing state and subsequent potential to reduce water scarcity. Conventional hybrid desalination systems (NF-RO-MSF, MED-AD, FO-MED, MSF-MED, RO-MED, RO-MSF and RO-MD) are briefly discussed. This study reveals that the integration of solar thermal energy with desalination has a great potential to substantially reduce greenhouse emissions besides providing the quality and/or quantity of potable water in cost-effective ways. Due to its abundant availability with minimal/no carbon footprint and the ability to generate both thermal and electrical energy, solar energy is considered better than other renewable energy technologies. The findings further suggest that hybrid desalination systems are technically sound and environmentally suitable; however, a significant study of the research process and development is still required to make this technology efficient and economically viable